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Effects of cyclic carboxylate nucleating agents on nucleus density and crystallization behavior of isotactic polypropylene

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成果类型:
期刊论文
作者:
Zhang, Yue-Fei*;Hou, Huan-Huan;Guo, Li-Hua
通讯作者:
Zhang, Yue-Fei
作者机构:
[Zhang, Yue-Fei; Guo, Li-Hua; Hou, Huan-Huan] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, 960 South Wanjiali Rd, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Zhang, Yue-Fei] C
Changsha Univ Sci & Technol, Sch Chem & Biol Engn, 960 South Wanjiali Rd, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Crystallization behavior;Isotactic polypropylene;Cyclic carboxylate nucleating agent;Nucleus density
期刊:
Journal of Thermal Analysis and Calorimetry
ISSN:
1388-6150
年:
2018
卷:
131
期:
2
页码:
1483-1490
基金类别:
Acknowledgements This work was financially supported by National Natural Science Foundation of China (Grant No. 21376031) and Scientific Research Fund of Hunan Provincial Education Department (Grant No. 16A004).
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
Isothermal crystallization behavior of isotactic polypropylene (iPP) nucleated with three cyclic carboxylate nucleating agents, namely, sodium bicyclic[2,2,1] heptane dicarboxylate (HPN-68), sodiumbenzoate (Be-Na), and sodium salt of hexahydrophthalic acid (HHPA-Na), was investigated by using differential scanning calorimetry. The classical Avarmi method was used to evaluate the isothermal crystallization behavior of iPP. The nucleus density was obtained by the calculation model of Lamberti based on the Avrami method of crystallization kinetics...

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