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Enhanced Photovoltaic Performance of Asymmetrical Benzo Dithiophene Homopolymer Donor Materials in Nonfullerene Acceptor-Based Organic Photovoltaics

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成果类型:
期刊论文
作者:
Xu, Wei;Du, Li;Du, Zhengkun;He, Wei;Li, Hongxiang;...
通讯作者:
Cao, Z;Yu, DH;Du, ZK
作者机构:
[Xu, Wei; Cao, Zhong] Changsha Univ Sci & Technol, Sch Chem & Chem Engn, Hunan Prov Key Lab Mat Protect Elect Power & Trans, Hunan Prov Key Lab Cytochem, Changsha 410114, Peoples R China.
[Yu, Donghong; Xu, Wei] Aalborg Univ, Dept Chem & Biosci, Fredrik Bajers Vej 7H, DK-9220 Aalborg, Denmark.
[Du, ZK; Du, Li; Du, Zhengkun] Shandong Univ Sci & Technol, Coll Energy Storage Technol, Qingdao 266590, Peoples R China.
[Li, Hongxiang; Cheng, Pei; He, Wei] Sichuan Univ, Dept Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China.
[Li, Guojuan] Natl Antidrug Lab Sichuan Reg Ctr, Chengdu 610206, Peoples R China.
通讯机构:
[Du, ZK ] S
[Yu, DH ] A
[Cao, Z ] C
Changsha Univ Sci & Technol, Sch Chem & Chem Engn, Hunan Prov Key Lab Mat Protect Elect Power & Trans, Hunan Prov Key Lab Cytochem, Changsha 410114, Peoples R China.
Aalborg Univ, Dept Chem & Biosci, Fredrik Bajers Vej 7H, DK-9220 Aalborg, Denmark.
语种:
英文
关键词:
benzodithiophene;donor polymer;photovoltaic;organic solar cells;power conversion efficiency
期刊:
Molecules
ISSN:
1420-3049
年:
2024
卷:
29
期:
6
页码:
1332-
基金类别:
Conceptualization, Z.D., Z.C. and D.Y.; methodology, W.X., Z.D. and P.C.; software, H.L.; validation, G.L., L.D. and W.H.; formal analysis, W.X. and G.L.; investigation, W.X., W.H. and H.L.; resources, P.C. and C.Y.; data curation, W.X. and H.L.; writing—original draft preparation, W.X. and Z.C.; writing—review and editing, W.X., Z.C. and D.Y.; visualization, C.Y. and P.C.; supervision, P.C., Z.C. and D.Y.; project administration, P.C. and D.Y.; funding acquisition, D.Y. All authors have read and agreed to the published version of the manuscript. This research was funded by the China Scholarship Council (CSC No. 201908510136) and the Shandong Provincial Natural Science Foundation, China (ZR2023MB132). The authors also thank Beijing Synchrotron Radiation Facility (BSRF) 1W1A for the 2D GIWAXS measurements. Support from the Sino-Danish Center for Education and Research is fully acknowledged.
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
摘要:
Although much promising synthetic progress in conjugated polymer-based organic solar cells (OSCs) has resulted in significant improvement in power conversion efficiencies (PCEs) of from over 15 to >19.0% in the last five years, the sophisticated and complex reactions from at least two families' monomers with remarkably different electron push-pull effects could still pose an unavoidable material burden for the commercialization of OSCs in the coming future. Therefore, the method of preparing a homopolymer from a sole monomer would significantly...

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