Synthesis and Crystal Structure of a Dibridged Dinuclear Cadmium(II) Complex with Schiff Base 2-[(2-Dimethylaminoethylimino)methyl]-6-methoxyphenol

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成果类型：

期刊论文

作者：

Peng, San-Jun*;Hou, Hai-Yun;Wang, Qiong;Yang, Tao;Zhou, Cong-Shan

通讯作者：

Peng, San-Jun

作者机构：

[Peng, San-Jun; Wang, Qiong] Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha, Hunan, Peoples R China.

[Hou, Hai-Yun] Xian Polytechn Univ, Coll Environm & Chem Engn, Xian, Hunan, Peoples R China.

[Yang, Tao; Zhou, Cong-Shan] Hunan Inst Sci & Technol, Dept Chem & Chem Engn, Yueyang, Hunan, Peoples R China.

[Peng, San-Jun; Wang, Qiong] Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China.

[Hou, Hai-Yun] Xian Polytech Univ, Coll Environm & Chem Engn, Xian, Shanxi, Peoples R China.

通讯机构：

[Peng, San-Jun] C

Changsha Univ Sci & Technol, Coll Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China.

语种：

英文

关键词：

cadmium;crystal structure;Schiff base;synthesis

期刊：

Inorganic and Nano-Metal Chemistry

ISSN：

2470-1556

年：

2008

卷：

期：

页码：

746-749

DOI：

10.1080/15533170802525803

基金类别：

Scientific Research Fund of Hunan Provincial Education Department [08B031]

机构署名：

本校为第一且通讯机构

院系归属：

化学与生物工程学院

摘要：

A tetradentate Schiff base compound 2-[(2-dimethylaminoethylimino)methyl]-6-methoxyphenol (HL) reacts with cadmium nitrate and ammonium thiocyanate in a methanol solution to give a dinuclear complex [Cd2L2(μ1,1-NCS)(NCS)(OH2)]. The complex was characterized by physico-chemical and spectroscopic methods. X-ray crystallography indicates that each Cd(II) atom is in a distorted octahedral coordination. The two metal atoms are bridged by one phenolate O and one ...

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Synthesis and Crystal Structure of a Dibridged Dinuclear Cadmium(II) Complex with Schiff Base 2-[(2-Dimethylaminoethylimino)methyl]-6-methoxyphenol

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