This work was financially supported by the National Natural Science Foundation of China (Nos. 21501015, 51604042, 31527803, and 21545010). Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
物理与电子科学学院
摘要:
Extending the working voltage is an effective approach to enhance the reversible capacity of LiNi1-x-yCoxMnyO2 layered oxide cathode materials. However, the layered Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode suffers a severe structural instability and rapid capacity decrease during high-voltage cycling (4.6 V). In order to solve these problems, the surface coating layer of SnO2 is successfully prepared via a one-step synthesis way followed with a high temperature calcination method. The 1.0% SnO2-modified LiNi0.8Co0.1Mn0.1O2 delivers a much higher capacity retention (83.63%) compared with pristine sa...