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Alleviating Surface Degradation of Nickel-Rich Layered Oxide Cathode Material by Encapsulating with Nanoscale Li-Ions/Electrons Superionic Conductors Hybrid Membrane for Advanced Li-Ion Batteries

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成果类型:
期刊论文
作者:
Li, Lingjun;Xu, Ming;Yao, Qi;Chen, Zhaoyong;Song, Liubin;...
通讯作者:
Lai, Yanqing
作者机构:
[Yao, Qi; Chen, Zhaoyong; Li, Lingjun] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.
[Wang, Peng; Xu, Ming; Zhang, Zhian; Gao, Chunhui; Yu, Ziyang; Lai, Yanqing] Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China.
[Song, Liubin] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Lai, Yanqing] C
Cent S Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China.
语种:
英文
关键词:
hybrid nanomembrane;lithium residue;nickel-rich;cathode material;lithium-ion batteries
期刊:
ACS Applied Materials & Interfaces
ISSN:
1944-8244
年:
2016
卷:
8
期:
45
页码:
30879-30889
基金类别:
The authors are thankful for the financial support of the National Natural Science Foundation of China (Contract Nos. 51304031), the Project of Innovation-driven Plan in Central South University (2015CXS018) (2015CX001), and the State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China.
机构署名:
本校为第一机构
院系归属:
化学与生物工程学院
材料科学与工程学院
摘要:
Nickel-rich layered oxide cathode materials for advanced lithium-ion batteries have received much attention recently because of their high specific capacities and significant reduction of cost. However, these cathodes are facing a fundamental challenge of loss in performance as a result of surface lithium residue, side reactions with the electrolyte and structure rearrangement upon long-term cycling. Herein, by capturing the lithium residue on the surface of LiNi0.8Co0.1Mn0.1O2 (NCM) cathode material as Li source, we propose a hybrid coating st...

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