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环氧沥青固化反应机理及施工控制性能研究

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成果类型:
期刊论文
论文标题(英文):
Study of Curing Reaction Mechanism and Construction Control Performance of Epoxy Asphalt
作者:
黄红明;曾国东;徐伟;李水金;周志刚
作者机构:
[周志刚] School of Traffic and Transportation Engineering, Changsha University of Science & Technology, Changsha, 410004, China
[Zeng G.] Foshan Transportation Science and Technology Co., Ltd., Foshan, 528041, China
Foshan Road and Bridge Supervision Station Co., Ltd., Foshan, 528041, China
[徐伟] School of Civil Engineering and Transportation, South China University of Technology, Guangzhou, 510641, China
[李水金] Zhuhai Couple Coast Construction Co., Ltd., Zhuhai, 519000, China
语种:
中文
关键词:
环氧沥青;微观形貌;固化反应;热塑性热固性;施工控制
关键词(英文):
Asphalt;Curing;Fluorescence microscopy;Mixtures;Scanning electron microscopy;Thermosets;Construction control;Construction temperatures;Cross-linked networks;Curing reaction mechanism;Health maintenances;Holding temperatures;Strength development;Transition mechanism;Epoxy resins
期刊:
建筑材料学报
ISSN:
1007-9629
年:
2020
卷:
23
期:
4
页码:
941-947
基金类别:
国家科技支撑计划项目(2011BAG07B03); 佛山市科技创新项目(2018AB003841);
机构署名:
本校为第一机构
院系归属:
交通运输工程学院
摘要:
采用扫描电子显微镜和荧光显微镜观察环氧沥青(N-EA)的微观形貌,探索分析N-EA的固化反应特性及热塑性-热固性转变机理,研究最佳混合树脂(环氧树脂与固化剂的混合物)掺量N-EA混合料的容留温度、容留时间和强度发展规律等施工控制性能.结果表明:37%混合树脂掺量为N-EA热塑性-热固性转变临界点;38%混合树脂掺量N-EA形成交联网络结构,环氧树脂为连续相,表现为热固性;50%混合树脂掺量N-EA形成均匀、密实的三维交联网络结构,沥青在环氧树脂中起增韧作用;N-EA混合料的容留温度和容留时间控制范围较宽,在165~185℃容留温度下最长容留时间可达3.0h;N-EA混合料具有较高的弯拉模量和变形性能,175℃容留...
摘要(英文):
Scanning electron microscopy and fluorescence microscopy were applied to observe the micromorphology of new epoxy asphalt N-EA with a view to analyze the curing reaction and transition mechanism between thermoplasticity and thermoset of N-EA. Through this method, the construction control performance of N-EA epoxy asphalt was investigated under the best mixed resin dosage condition, such as mixing holding temperature, construction control time, strength development, etc. The results showed that 37% mixed resin is the inversion amount of N-EA cha...

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