Design and construction of a heterojunction structured photocatalyst with efficient electron transfer is of great significance. In this work, we prepared a unique Z-scheme Ag/Agln(5)S(8)/BiVO4 photocatalyst of which BiVO4 has highly exposed (040) crystal facets. Ag as an electronic medium to build a special and efficient electron transfer path. In addition, the surface plasmon resonance effect of Ag improves the sunlight utilization of photocatalyst, and Ag as an electron transport medium and co-catalyst enhances the photocatalytic ability of the photocatalyst. Under optimum reaction condition...