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Visible-light-induced deoxygenative C2-sulfonylation of quinoline: N -oxides with sulfinic acids

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成果类型:
期刊论文
作者:
Xie, Long-Yong;Fang, Tai-Gang;Tan, Jia-Xi;Zhang, Bo;Cao, Zhong;...
通讯作者:
He, Wei-Min
作者机构:
[Yang, Li-Hua; Fang, Tai-Gang; He, Wei-Min; Tan, Jia-Xi; Xie, Long-Yong] Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China.
[Zhang, Bo; Cao, Zhong] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Hunan, Peoples R China.
[Tan, Jia-Xi] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China.
通讯机构:
[He, Wei-Min] H
Hunan Univ Sci & Engn, Dept Chem, Yongzhou 425100, Peoples R China.
语种:
英文
期刊:
Green Chemistry
ISSN:
1463-9262
年:
2019
卷:
21
期:
14
页码:
3858-3863
基金类别:
We are grateful for financial support from the post-funded projects of Hunan University of Science and Engineering and Hunan Provincial Natural Science Foundation of China (No. 2019JJ20008).
机构署名:
本校为其他机构
院系归属:
化学与生物工程学院
摘要:
The first example of visible-light-induced deoxygenative C2-sulfonylation of quinoline N-oxides with sulfinic acids in the presence of an organic dye as the catalyst was developed. The reaction conditions are eco-friendly and mild, employing ambient air as the sole oxidant and aqueous acetone solution as the solvent. This approach requires only a very low catalyst loading, allowing gram-scale preparation as well as late-stage modification of biologically active compounds beari...

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