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Enhanced mechanism of carbamazepine degradation by electrochemical activation of persulfate in flow-through system

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成果类型:
期刊论文
作者:
Cai, Jingju;Xie, Jinxin;Xing, Liping;Zhou, Lean;Zhang, Qizhan;...
通讯作者:
Minghua Zhou
作者机构:
[Xing, Liping; Cai, Jingju] Cent South Univ Forestry & Technol, Coll Environm Sci & Engn, Changsha 410007, Peoples R China.
[Zhang, Qizhan; Zhou, Minghua; Cai, Jingju; Xie, Jinxin] Nankai Univ, Key Lab Pollut Proc & Environm Criteria, Minist Educ, Coll Environm Sci & Engn, Tianjin 300350, Peoples R China.
[Zhou, Lean] Changsha Univ Sci & Technol, Key Lab Dongting Lake Aquat Ecoenvironm Control &, Sch Hydraul Engn, Changsha 410114, Peoples R China.
通讯机构:
[Minghua Zhou] K
Key Laboratory of Pollution Process and Environmental Criteria, Ministry of Education, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China
语种:
英文
关键词:
TiO2 nanotubes;Co-doped boron and cobalt;Flow-through;Electrochemical activation of persulfate;Carbamazepine
期刊:
Separation and Purification Technology
ISSN:
1383-5866
年:
2022
卷:
301
页码:
122021
基金类别:
In order to compare the performance of CBZ degradation at different modes of flow-through mode with PS and without PS and beaker system for EA-PS system, the CBZ removal, PS decomposition and OH production were shown in Fig. 1. In the flow-through system without PS the CBZ removal at 120 min was only 36 %, and once PS was added, it was improved to 94 %. While in beaker system for the CBZ removal was 86 %, and the PS decomposition was slowly than that in flow-through mode, indicating less SO4−
机构署名:
本校为其他机构
院系归属:
水利工程学院
摘要:
Degradation of carbamazepine (CBZ) was first conducted by electrochemical activation of persulfate (PS) in flow-through system using boron and cobalt co-doped TiO2 nanotubes (B, Co-TNT) as the anode and carbon felt (CF) as the cathode, achieving a higher removal efficiency than that in beaker mode ascribed to the higher PS decomposition for center dot OH production. Different operating parameters including applied current, initial pH, PS concentration and flow rate were explored, supporting that high current, acidic condition, lofty PS concentration and flow rate were beneficial for the remova...

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