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Composite polymer electrolytes incorporating two-dimensional metal-organic frameworks for ultralong cycling in solid-state lithium batteries

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成果类型:
期刊论文
作者:
Jiang, Han;Du, Yongqian;Liu, Xuanyu;Kong, Jiangrong;Huang, Meiqi;...
通讯作者:
Kong, JR
作者机构:
[Huang, Meiqi; Zhou, Tao; Kong, Jiangrong; Jiang, Han; Du, Yongqian; Liu, Xuanyu] Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Efficient & Clean Utilizat Mang, Changsha 410083, Peoples R China.
[Liu, Peng] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Peoples R China.
通讯机构:
[Kong, JR ] C
Cent South Univ, Coll Chem & Chem Engn, Hunan Prov Key Lab Efficient & Clean Utilizat Mang, Changsha 410083, Peoples R China.
语种:
英文
期刊:
Journal of Materials Chemistry A
ISSN:
2050-7488
年:
2023
基金类别:
This work was supported by National Natural Science Foundation of China (21506259); Natural Science Foundation of Hunan Province (2023JJ30030); Natural Science Foundation of Changsha (kq2208223); Postgraduate Innovative Project of Central South University [21506259]; National Natural Science Foundation of China [2023JJ30030]; Natural Science Foundation of Hunan Province [kq2208223]; Natural Science Foundation of Changsha [QL20220039]; Postgraduate Innovative Project of Central South University; Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
Solid polymer electrolytes (SPEs) present substantial potential for use in solid-state lithium batteries; however, their authentic usability is presently curbed by their inadequate ionic conductivity and restricted lithium-ion mobility. Herein, a strategy to enhance the performance of poly(vinylidene fluoride) (PVDF) composite polymer electrolytes (CPEs) using two-dimensional cobalt-based ultrathin metal-organic framework nanosheet (CMS) with a high aspect ratio is proposed. At a CMS loading of 8 wt%, the obtained CPEs displayed a high ionic conductivity of 6.26 x 10-4 S cm-1 (28 degrees C). I...

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