In order to improve the toughness of Fe-B-C alloy, the effect of Rare earth (RE)-Ti-N composite modifcation on the microstructures and properties of Fe-B-C alloy was researched. The results showed that the solidification structures of Fe-B-C alloy is refined obviously and the distribution of structures is uniform after composite modification. Moreover, the compound containing boron and titanium appeared in Fe-B-C alloy containing RE-Ti-N. The compound containing boron and titanium was different from the network Fe2B in the common Fe-B-C alloy, whose distribution was broken network and lump. Af...