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1,3-Pentadiene-Assistant Living Anionic Terpolymerization: Composition Impact on Kinetics and Microstructure Sequence Primary Analysis

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成果类型:
期刊论文
作者:
Xiong, Qiaoqiao;Fu, Yawen;Xu, Jundong;Gu, Zhuowei;Peng, Chengjun;...
通讯作者:
Li, Lijun;Liu, K
作者机构:
[Li, Lijun; Gu, Zhuowei; Xiong, Qiaoqiao; Liu, Kun; Xie, Fengli; Li, An; Fu, Yawen; Cao, Yujie; Tan, Haoyun; Peng, Chengjun; Dai, Qiqi; Xu, Jundong] Hunan Inst Sci & Technol, Coll Chem & Chem Engn, Prov Key Lab Fine Petrochem Catalysis & Separat, Yueyang, Peoples R China.
[Yi, Wenjun] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410082, Peoples R China.
通讯机构:
[Li, LJ; Liu, K ] H
Hunan Inst Sci & Technol, Coll Chem & Chem Engn, Prov Key Lab Fine Petrochem Catalysis & Separat, Yueyang, Peoples R China.
语种:
英文
关键词:
kinetic analysis;living anionic technology;poly(1,3-pentadiene-co-syrene-co-1,1-diphenylethylene) resins;unique alternating strategy;“bond-forming initiation” theory
期刊:
Polymers
ISSN:
2073-4360
年:
2023
卷:
15
期:
9
页码:
2191-
基金类别:
Conceptualization, K.L.; methodology, A.L. and K.L.; validation, Q.X., Y.F., H.T., Q.D., Y.C. and F.X.; formal analysis, J.X., Z.G. and C.P.; investigation, Q.X., Y.F., Q.D., Y.C. and F.X.; resources, Z.G., C.P., H.T., Q.D., Y.C., F.X. and W.Y.; data curation, Q.X., Y.F. and H.T.; writing—original draft preparation, Z.G. and C.P.; writing—review and editing, L.L.; visualization, F.X. and W.Y.; supervision, J.X., L.L. and K.L.; project administration, J.X., A.L., L.L. and K.L.; funding acquisition, A.L., W.Y., L.L. and K.L. All authors have read and agreed to the published version of the manuscript. This research was funded by the National Natural Science Foundation of China (No. 21901070), the Natural Science Foundation of Hunan Province of China (No. 2019JJ50213, No. 2022JJ30279), and the financial support of the Educational Commission of Hunan Province of China (Nos. 20B263, 20B258, 20B268), as well as the Changsha Municipal Natural Science Foundation (kq2208219).
机构署名:
本校为其他机构
院系归属:
材料科学与工程学院
摘要:
The combination of a living anionic technology and a unique alternating strategy provided an exciting opportunity to prepare novel and well-defined poly(1,3-pentadiene-co-syrene-co-1,1-diphenylethylene) resins consisting of three alternating sequences of modules (A/B/C zwitterions). "A" being Styrene (St)/1,3-pentadiene (PD), "B" being diphenylethylene (DPE)/PD, "A" being DPE/St, respectively, A wide composition range of new polyolefin resins, i.e., poly (A-co-B), poly (A-co-C), and poly (B-co-C), with controlled molecular weight and very narro...

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