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A realistic skeletal mechanism for the oxidation of biodiesel surrogate composed of long carbon chain and polyunsaturated compounds

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成果类型:
期刊论文
作者:
Wu, Gang;Wang, Xin;Abubakar, Shitu;Li, Yuqiang*;Liu, Zhiqiang*
通讯作者:
Liu, Zhiqiang;Li, Yuqiang
作者机构:
[Wang, Xin; Wu, Gang; Liu, Zhiqiang] Changsha Univ Sci & Technol, Coll Automot & Mech Engn, Changsha 410114, Peoples R China.
[Abubakar, Shitu] Cent South Univ, Coll Mech & Elect Engn, Changsha 410083, Peoples R China.
[Li, Yuqiang] Cent South Univ, Sch Energy Sci & Engn, Changsha 410083, Peoples R China.
通讯机构:
[Liu, Zhiqiang; Li, Yuqiang] C
Changsha Univ Sci & Technol, Coll Automot & Mech Engn, Changsha 410114, Peoples R China.
Cent South Univ, Sch Energy Sci & Engn, Changsha 410083, Peoples R China.
语种:
英文
关键词:
Core sub;Ester group;Fuel;Heavy methyl esters;Mechanism;Polyunsaturated degree;Real biodiesel;Related sub
期刊:
Fuel
ISSN:
0016-2361
年:
2021
卷:
289
页码:
119934
基金类别:
This work is supported by National Natural Science Foundation of China (Grant No. 51976016 and 51806250). We also thank to the support by the Natural Science Foundation of Hunan Province, China (Grant No.2020JJ4616) and the Research Foundation of Education Bureau of Hunan Province, China (Grant No. 18B149).
机构署名:
本校为第一且通讯机构
院系归属:
汽车与机械工程学院
摘要:
To obtain a realistic reduced reaction model for the combustion of biodiesel in compression ignition engine, the heavy methyl esters with long carbon chain and polyunsaturated degree were used to characterize real biodiesel fuel in this study. Methyl palmitate (MHD), methyl stearate (MOD), methyl linoleate (MOD9D12D), methyl–5–decenoate (MD5D) and n–decane were selected as the surrogate of biodiesel. A skeletal mechanism with 187 species and 982 reactions was developed for the oxidation of biodiesel surrogate using the decoupling methodology...

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