Metal-free I2O5-mediated oxidative synthesis of sulfonylated benzofurans through cyclization reaction of 1,6-enynes and arylsulfonylhydrazides

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成果类型：

期刊论文

作者：

Wang, Leilei;Zhang, Yulong;Zhang, Min;Bao, Pengli;Lv, Xiaoxia;...

通讯作者：

Wei, Wei;Zhao, Xiaohui

作者机构：

[Zhang, Yulong; Lv, Xiaoxia; Bao, Pengli; Wei, Wei; Wang, Leilei; Zhang, Min] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.

[Liu, Hai-Gang] Chem Design & Res Inst Qinghai Prov, Xining 810008, Qinghai, Peoples R China.

[Zhao, Xiaohui] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.

[Zhao, Xiaohui] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.

[Li, Jiang-Sheng] Changsha Univ Sci & Technol, Sch Chem & Food Engn, Changsha 410114, Hunan, Peoples R China.

通讯机构：

[Wei, Wei] Q

[Zhao, Xiaohui] C

Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.

Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.

Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.

语种：

英文

关键词：

1,6-Enynes;Oxidative cyclization;Sulfonylated benzofurans;Sulfonylhydrazides

期刊：

Tetrahedron Letters

ISSN：

0040-4039

年：

2019

卷：

期：

页码：

1845-1848

DOI：

10.1016/j.tetlet.2019.06.017

基金类别：

International Cooperation Project of Qinghai Province [2018-HZ-806, 2018-HZ-815]; Special Project of Achievements Conversion of Qinghai Provincial Science and Technology Department [2016-GX-116]; Qinghai Key Laboratory of Tibetan Medicine Research [2017-Z1-Y11]; Natural Science Foundation of Shandong ProvinceNatural Science Foundation of Shandong Province [ZR2018MB009]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21601106]

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摘要：

A simple I2O5-mediated method for the construction of sulfonylated benzofurans has been developed under metal-free conditions. The present reaction can be efficiently achieved through the oxidative cyclization of 1,6-enynes and arylsulfonylhydrazides, which provides an attractive approach to a series of sulfonylated benzofurans in moderate to good y...

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Metal-free I2O5-mediated oxidative synthesis of sulfonylated benzofurans through cyclization reaction of 1,6-enynes and arylsulfonylhydrazides

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