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A Novel Cerium(IV)-Based Metal-Organic Framework for CO2 Chemical Fixation and Photocatalytic Overall Water Splitting

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成果类型:
期刊论文
作者:
Gu, Jia-Xin;Chen, Hao;Ren, Yu;Gu, Zhi-Gang;Li, Guangli;...
通讯作者:
Jin, Hong-Guang
作者机构:
[Ren, Yu; Yang, Xin-Yu; Jin, Hong-Guang; Xu, Wen-Jie; Gu, Jia-Xin; Wen, Jian-Xin] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
[Gu, Zhi-Gang; Chen, Hao] Univ Chinese Acad Sci, Beijing 100049, Peoples R China.
[Li, Guangli; Wu, Jing-Tao] Hunan Univ Technol, Coll Life Sci & Chem, Zhuzhou 412007, Peoples R China.
通讯机构:
[Jin, Hong-Guang] C
Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
CSUST-3;metal-organic frameworks;carbon dioxide fixation;photocatalysis;water splitting
期刊:
ChemSusChem
ISSN:
1864-5631
年:
2022
卷:
15
期:
1
页码:
e202102368
基金类别:
This work was financially supported by the program from the Outstanding Youth Project of Education Department of Hunan Province (Grant No. 20B023), the Natural Science Foundation of Hunan Province (Grant No. 2020JJ5567), and the Science Booster Program of Changsha University of Science and Technology.
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Cerium (IV)-based metal-organic frameworks (MOFs) are highly desirable due to their unique potential in fields such as redox catalysis and photocatalysis. However, due to the high reduction potential of CeIV species in solution, it is still a great challenge to synthesize CeIV-MOFs with novel structures, which are extremely dominated by the hexanuclear Ce−O cluster inorganic building units (IBUs). Herein, a Ce−O IBU chain containing CeIV-MOF, CSUST-3 (CSUST: Changsha University of Science and Technology), was successfully prepared using the k...

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