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Catalyst-free visible-light-initiated oxidative coupling of aryldiazo sulfones with thiols leading to unsymmetrical sulfoxides in air

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成果类型:
期刊论文
作者:
Liu, Qishun;Wang, Leilei;Yue, Huilan;Li, Jiang-Sheng;Luo, Zidan;...
通讯作者:
Wei, Wei
作者机构:
[Wei, Wei; Wang, Leilei; Liu, Qishun] Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.
[Yue, Huilan; Wei, Wei] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.
[Yue, Huilan; Wei, Wei] Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.
[Li, Jiang-Sheng] Changsha Univ Sci & Technol, Sch Chem & food Engn, Changsha 410114, Hunan, Peoples R China.
[Luo, Zidan] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China.
通讯机构:
[Wei, Wei] Q
[Wei, Wei] C
Qufu Normal Univ, Sch Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China.
Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Prov Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.
Chinese Acad Sci, Northwest Inst Plateau Biol, Key Lab Tibetan Med Res, Xining 810008, Qinghai, Peoples R China.
语种:
英文
期刊:
Green Chemistry
ISSN:
1463-9262
年:
2019
卷:
21
期:
7
页码:
1609-1613
基金类别:
Natural Science Foundation of Shandong ProvinceNatural Science Foundation of Shandong Province [ZR2018MB009]; International Cooperation Project of Qinghai Province [2018-HZ-806, 2017-HZ-806]; Qinghai Key Laboratory of Tibetan Medicine Research [2017-ZJ-Y11]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21302109]
机构署名:
本校为其他机构
摘要:
A facile and efficient visible-light-driven method has been developed to construct sulfoxides via oxidative coupling of aryldiazo sulfones with thiols using the O2 in air as the oxidant. This reaction could be performed at room temperature under catalyst- and additive-free conditions. The present methodology offers a mild and environmentally benign approach to obtain a library of sulfoxides in good yields with favorable functional group ...

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