Anion Texturing Towards Dendrite-Free Zn Anode for Aqueous Rechargeable Batteries

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期刊论文

作者：

Yuan, Du*;Zhao, Jin;Ren, Hao;Chen, Yingqian;Chua, Rodney;...

通讯作者：

Yuan, Du;Srinivasan, Madhavi

作者机构：

[Yuan, Du] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.

[Ren, Hao; Edison, Eldho; Yuan, Du; Manalastas, William, Jr.; Srinivasan, Madhavi; Chua, Rodney; Jie, Ernest Tang Jun; Cai, Yi; Yuan, D; Srinivasan, M] Nanyang Technol Univ, Sch Mat Sci & Engn, Block N4-1,50 Nanyang Ave, Singapore 639798, Singapore.

[Zhao, Jin] Nanjing Univ Posts & Telecommun, Sch Mat Sci & Engn, Displays & Inst Adv Mat, Jiangsu Key Lab Organ Elect & Informat, Nanjing 210023, Peoples R China.

[Wong, Ming Wah; Chen, Yingqian] Natl Univ Singapore, Dept Chem, 3 Sci Dr 3, Singapore 117543, Singapore.

通讯机构：

[Yuan, Du] C

[Yuan, D; Srinivasan, M] N

Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China.

Nanyang Technol Univ, Sch Mat Sci & Engn, Block N4-1,50 Nanyang Ave, Singapore 639798, Singapore.

语种：

英文

关键词：

deposition;sulfonate;texture;zinc ion battery;Zn

期刊：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ISSN：

1433-7851

年：

2021

卷：

期：

页码：

7213-7219

DOI：

10.1002/anie.202015488

基金类别：

The authors appreciate the financial support by National Research Foundation of Singapore (NRF) investigatorship award number NRF‐NRFI2017‐08 (NRF2016NRF‐NRFI001‐22). The authors would like to acknowledge the Facility for Analysis, Characterization, Testing and Simulation, Nanyang Technological University, Singapore, for use of their electron microscopy/X‐ray facilities.

机构署名：

本校为第一且通讯机构

院系归属：

材料科学与工程学院

摘要：

The reversibility of metal anode is a fundamental challenge to the lifetime of rechargeable batteries. Though being widely employed in aqueous energy storage systems, metallic zinc suffers from dendrite formation that severely hinders its applications. Here we report texturing Zn as an effective way to address the issue of zinc dendrite. An in-plane oriented Zn texture with preferentially exposed (002) basal plane is demonstrated via a sulfonate anion-induced electrodeposition, noting no solid report on (002) textured Zn till now. Anion-induced...

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Anion Texturing Towards Dendrite-Free Zn Anode for Aqueous Rechargeable Batteries

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