期刊论文

Zhang, Yue-Fei

英文

Macromolecular Reaction Engineering

1862-832X

2021

15

1

10.1002/mren.202000046

This work was supported by Hunan Provincial Natural Science Foundation of China (Grant No. 2019JJ50652), Scientific Research Fund of Hunan Provincial Education Department (Grant No. 18C0197), Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation (Grant No. 2019CL01), and the Changsha Science and Technology Project (Grant No. kq1801163). This work was supported by Hunan Provincial Natural Science Foundation of China (Grant No. 2019JJ50652), Scientific Research Fund of Hunan Provincial Education Department (Grant No. 18C0197), Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation (Grant No. 2019CL01), and the Changsha Science and Technology Project (Grant No. kq1801163).

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A radical polymerization reaction of acrolein is reported in this article. The free radical initiator which can effectively promote the free radical polymerization of acrolein is screened out. The optimal conditions of the reaction are investigated and the yield could be up to 93.67%, in which the ratio of initiator to monomer is 1:50, monomer concentration is 7.5molL−1, reaction temperature is 50°C, and the reaction time is 6h. The structure characterizations of the obtained polymers are performed using hydrogen nuclear magnetic resonance sp...