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Enhanced photocatalytic activity of Te-doped Bi2MoO6 under visible light irradiation: Effective separation of photogenerated carriers resulted from inhomogeneous lattice distortion and improved electron capturing ability

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成果类型:
期刊论文
作者:
Chen, Shuguang*;Li, Yuhan;Wu, Zixu;Wu, Baoxin;Li, Haibin;...
通讯作者:
Chen, Shuguang
作者机构:
[Li, Fujin; Li, Haibin; Wu, Zixu; Wu, Baoxin; Li, Yuhan; Chen, Shuguang] Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
通讯机构:
[Chen, Shuguang] C
Changsha Univ Sci & Technol, Sch Mat Sci & Engn, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Te-doped Bi2MoO6;Lattice distortion;Electron capturing;Photocatalytic activity;Mechanism
期刊:
Journal of Solid State Chemistry
ISSN:
0022-4596
年:
2017
卷:
249
页码:
124-130
基金类别:
In summary, nanoflaky Te-doped Bi2MoO6 photocatalyst has been synthesized via a facile hydrothermal route, and nonmetal atoms Te are successfully incorporated into the Bi2MoO6 lattice with the substitution of Te4+ to Mo6+. Te-doping does not cause the detectable band gap narrowing of Bi2MoO6. However, inhomogeneous lattice distortion is determined to be more and more severe with increasing Te-doping concentration in Bi2MoO6, presenting larger changes in lattice parameter b and smaller changes
机构署名:
本校为第一且通讯机构
院系归属:
材料科学与工程学院
摘要:
Te-doped Bi2MoO6photocatalyst was hydrothermally synthesized, and nonmetal atoms Te were homogeneously incorporated into Bi2MoO6lattice with the substitution of Te4+to Mo6+. With increasing Te-doping concentration in Bi2MoO6, no detectable band-gap narrowing but more and more severe inhomogeneous lattice distortions were determined. The activity of Bi2MoO6photocatalyst was evaluated through methylene blue degradation under visible light irradiation (λ>410 nm) and was greatly enhanced by Te-doping. When Te-doped Bi2MoO6was synthesized at Te/Mo molar ratio of 7.5%, a maximum first...

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