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Characterization and electrochemical performance of lithium-active titanium dioxide inlaid LiNi0.5Co0.2Mn0.3O2 material prepared by lithium residue-assisted method

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成果类型:
期刊论文
作者:
Li, Lingjun;Chen, Zhaoyong*;Song, Liubin;Xu, Ming;Zhu, Huali;...
通讯作者:
Chen, Zhaoyong
作者机构:
[Zhu, Huali; Chen, Zhaoyong; Xu, Ming; Li, Lingjun; Gong, Li] Changsha Univ Sci & Technol, Sch Phys & Elect Sci, Changsha 410114, Hunan, Peoples R China.
[Zhang, Kaili; Li, Lingjun] City Univ Hong Kong, Dept Mech & Biomed Engn, Kowloon, Hong Kong, Peoples R China.
[Song, Liubin] Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410004, Hunan, Peoples R China.
通讯机构:
[Chen, Zhaoyong] C
Changsha Univ Sci & Technol, Sch Phys & Elect Sci, Changsha 410114, Hunan, Peoples R China.
语种:
英文
关键词:
Characterization;Diffusion;Fast Fourier transforms;High resolution transmission electron microscopy;Lithium;Lithium alloys;Lithium compounds;Lithium-ion batteries;Spectrometers;X ray diffraction;Electrochemical performance;Electrochemical test;Energy dispersive spectrometers;Gradient distributions;LiNi0.5Co0.2Mn0.3O2;LiTiO2-inlaid;Reversible capacity;Surface electronic conductivity;Manganese
期刊:
Journal of Alloys and Compounds
ISSN:
0925-8388
年:
2015
卷:
638
页码:
77-82
基金类别:
This work was financially supported by the National Natural Science Foundation of China (No. 51304031 ), the Hunan Provincial Natural Science Foundation of China (No. 14JJ3089 ), the Hunan Provincial Scientific Program of China (No. 2014FJ3159 ), the National Natural Science Foundation of China (No. 51302021 ), the Construct program of the Key Discipline in Hunan Province and Aid program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province .
机构署名:
本校为第一且通讯机构
院系归属:
化学与生物工程学院
物理与电子科学学院
摘要:
The lithium residues are consumed as raw materials to in-situ synthesize the LiTiO2-inlaid LiNi0.5Co0.2Mn0.3O2composites. The effects of various LiTiO2contents on the morphology, structure, and electrochemical properties of LiNi0.5Co0.2Mn0.3O2materials are investigated in detail. Energy dispersive spectrometer mapping, high-resolution transmission electron microscopy and fast Fourier transform analysis confirm that the spherical particles of LiNi0.5Co0.2Mn0.3O2are completely coated by crystalline LiTiO2phase; X-ray diffraction, cross-section SE...

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