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High-performance lithium-rich layered oxide material: Effects of preparation methods on microstructure and electrochemical properties

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成果类型:
期刊论文
作者:
Liu, Qiming;Zhu, Huali;Liu, Jun;Liao, Xiongwei;Tang, Zhuolin;...
通讯作者:
Chen, Zhaoyong
作者机构:
[Liu, Qiming; Yuan, Mengming; Chen, Zhaoyong; Liao, Xiongwei; Tang, Zhuolin; Liu, Jun; Zhou, Cankai; Duan, Junfei; Li, Lingjun] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China.
[Zhu, Huali] Changsha Univ Sci & Technol, Sch Phys & Elect Sci, Changsha 410114, Peoples R China.
通讯机构:
[Chen, Zhaoyong] C
Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410114, Peoples R China.
语种:
英文
关键词:
Cathode materials;Cathodes;Coprecipitation;Electric discharges;Ions;Lithium compounds;Oxalic acid;Sol-gel process;Sol-gels;0.5Li2MnO3.0.5LiMn0.8Ni0.1Co0.1O2;Coprecipitation method;Discharge specific capacity;Electrochemical performance;High energy densities;Lithium ion diffusion;Lithium-rich layered oxides;Oxalate co-precipitation method;Lithium-ion batteries
期刊:
Materials
ISSN:
1996-1944
年:
2020
卷:
13
期:
2
页码:
334
基金类别:
Funding: This work was supported by the National Natural Science Foundation of China (No. 51874048), the Research Foundation of Education Bureau of Hunan Province (No. 19A003) and Scientific Research Fund of Changsha Science and Technology Bureau (No. kq1901100) and Postgraduate Innovative Test Program of Hunan Province.
机构署名:
本校为第一且通讯机构
院系归属:
物理与电子科学学院
材料科学与工程学院
摘要:
Lithium-rich layered oxide is one of the most promising candidates for the next-generation cathode materials of high-energy-density lithium ion batteries because of its high discharge capacity. However, it has the disadvantages of uneven composition, voltage decay, and poor rate capacity, which are closely related to the preparation method. Here, 0.5Li2MnO3-0.5LiMn0.8Ni0.1Co0.1O2 was successfully prepared by sol-gel and oxalate co-precipitation methods. A systematic analysis of the materials shows that the 0.5Li2MnO3.0.5LiMn0.8Ni0.1Co0.1O2 prep...

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